SLOVYANSK, Ukraine (CNN) -

Ten Russian soldiers were detained in the Donetsk region of eastern Ukraine, that country's Security Service said Tuesday, as tensions simmered over the conflict between Ukrainian forces and pro-Russian rebels.

The Russian soldiers were captured with documents and weapons on them, the Security Service said.

Moscow has repeatedly denied claims by Kiev that it has sent troops and weapons over the border into Ukraine, where the Ukrainian military is fighting pro-Russian rebels.

Russia's state-run RIA Novosti news agency cited a source in the Russian Defense Ministry as saying the soldiers had been patrolling the border and "most likely crossed by accident" at an unmarked point.

The development came as Ukrainian President Petro Poroshenko and his Russian counterpart, Vladimir Putin, met for the first time since June.

The two Presidents agreed that they need to "renew our dialogue," Putin said, according to a CNN translation.

Putin said the meeting was "positive."

The two leaders are in Minsk, the capital of Belarus, for talks related to the Eurasian Customs Union, a trade bloc made up of Russia, Belarus and Kazakhstan -- with the crisis in Ukraine expected to dominate.

As the talks started, Poroshenko said "the fate of the world and Europe" could be decided in Minsk. "We must jointly find the only right decision. Peace on the continent depends on it," he said, according to his office.

Senior European Union officials, headed by EU foreign policy chief Catherine Ashton, are also in Minsk for the summit.

"The EU is attending to see if discussions can help create momentum for a new political solution to the crisis in Ukraine," said Ashton's spokeswoman, Maja Kocijancic.

Putin told reporters that Russia couldn't be involved in ceasefire talks because those discussions should be between Kiev and separatists in eastern Ukraine. Moscow is willing to assist, he added.

Putin: Military escalation won't solve crisis

Putin was cited by Russian state media as telling fellow leaders that the crisis in Ukraine "cannot be solved through further escalation of the military scenario."

He said Russia was "ready to exchange opinions" on the conflict and urged dialogue to find a peaceful resolution, state news agency ITAR-Tass reported.

Earlier, Poroshenko spoke with Ashton about the situation in his country's east and the detention of the 10 Russian soldiers, his office said.

He urged the world to support Ukraine and its efforts to secure its border with Russia "to prevent cross-border infiltration of weapons, military equipment and mercenaries." This, he said, would swiftly resolve the situation.

The conflict was first sparked last year by a political crisis over whether Ukraine would seek closer ties with Europe or with Russia. The ouster of pro-Moscow President Viktor Yanukovych in February was followed by Russia's annexation of Ukraine's Crimea region in March and a declaration of independence by separatist leaders in the Donetsk and Luhansk regions.

Poroshenko in June signed a landmark EU trade pact, despite opposition from Russia.

On Tuesday, after meeting with Ashton, the President said Ukraine would ratify the Association Agreement with the European Union in September and immediately send the ratification documents to Brussels.

The move "is in no way aimed against anyone," Poroshenko said, according to a statement from his office. "Instead, the agreement will positively affect relations with all our neighbors, especially in the economic sphere. We would like our international partners to accept our decision."

He added that parliamentary elections scheduled for October 26 should not affect the EU agreement. Poroshenko's trip to Belarus comes a day after he dissolved Ukraine's parliament.

However, Putin warned that it would cost Ukraine billions of euros to try to meet EU trade standards and that Russia, Belarus and Kazakhstan would also lose out. Ukrainian imports would no longer be given preferential treatment, he added.

It's not yet been confirmed whether Putin and Poroshenko, who last met briefly during D-Day commemorations in France, will hold bilateral talks while in Minsk.

'I just want to survive'